郝文燕, 女,中共党员,理学博士,副教授。2015年毕业于江西师范大学有机化学专业。2004年7月至今于bet365取款要多久工作,主要从事有机化学的教学和科研工作。主讲《高等有机化学》、《药物化学》、《精细有机合成实验》、《大学化学基础》、《文献检索》等本科生及研究生课程。
联系方式:手机:18970869895
E-mail:wenyanhao@jxnu.edu.cn
研究方向:
1. 廉价金属催化的氧化偶联反应。
2. 过渡金属催化的串联反应合成小分子杂环化合物。
在研项目:
1. 主持江西师范大学博士启动基金项目(廉价金属镍催化的异腈插入惰性芳基碳杂键反应研究)
2. 主持江西省教育厅项目(镍催化的分子内异腈插入串联反应合成含氮杂环化合物)
3. 主持江西师范大学校管科研计划项目(功能化MCM-41负载钯配合物催化剂的碳-杂键形成反应研究)
4. 参与江西省教育厅项目重点项目(基于MCM-41负载铜配合物催化的碳-碳键和碳-杂键形成反应研究)
已完成科研项目:
近几年发表论文:
1. Zou fei hua, Xuwen Chen, Wenyan Hao,* An efficient synthesis of iminoisoindolione derivatives by cobalt-catalyzed oxidative isocyanide insertion Tetrahedron 2017, 73, 758-763.
2. Wenyan Hao,* Xiaoyan Sang, Jing Jiang, Mingzhong Cai Copper(I)-catalyzed cascade reaction of 2-haloaryl isothiocyanates with isocyanides: A strategy to construct benzo[d]imidazo[5,1-b]thiazoles Tetrahedron lett. 2016,1511-1514.
3. Wenyan Hao,* Xiaoyan Sang, Yunsheng Xiao, Mingzhong Cai A cascade reaction of o-alkenylphenyl carbodiimides with isocyanides by copper catalysis: direct construction of 4,5-dihydroimidazo[1,5-a]quinazolines Tetrahedron lett. 2016, 4207-4209.
4. Wenyan Hao, Jun Tian, Wu Li, Renyi Shi, Zhiliang Huang, Aiwen Lei* Nickel-Catalyzed Oxidative C-H/N-H Isocyanide Insertion: an Efficient Synthesis of Iminoisoindolione Derivatives Chemistry: an Asian Journal 2016, 1664-1667.
5. Wenyan Hao, Haiyi Liu, Lin Yin, Mingzhong Cai* Phosphine-Free, Hetero- geneous Palladium-Catalyzed Atom-Efficient Carbonylative Cross- Coupling of Triarylbismuths with Aryl Iodides: Synthesis of Biaryl Ketones J. Org. Chem. 2016, 4244–4251
6. Wenyan Hao,* Jian Huang, Shanshan Jie, Mingzhong Cai* A Highly Efficient Copper(I)-Catalyzed Cascade Reaction of o-Alkenylphenyl Isothiocyanates with Isocyanides Leading to 5H-Benzo[d]imidazo[5,1-b][1,3]thiazines Eur. J. Org. Chem. 2015, 6655–6660.
7. Wenyan Hao, Yunyun Liu* C–H bond halogenation catalyzed or mediated by copper: an overview Beilstein J. Org. Chem. 2015, 11, 2132–2144.
8. Wenyan Hao, Jiangbo Zeng, Mingzhong Cai* The copper(I)-catalyzed tandem reaction of o-alkynylphenyl isothiocyanates with isocyanides: a rapid synthesis of 5H-benzo[d]-imidazo-[5,1-b][1,3]thiazines. Chem. Commun. 2014, 50, 11686-11689.
9. Wenyan Hao, Yuanyuan Jiang, Mingzhong Cai* Synthesis of indolyl imidazole derivatives via base-promoted tandem reaction of N?[2-(1-alkynyl)phenyl]carbodiimides with isocyanides. J. Org. Chem. 2014, 79, 3634-3640.
10. Wenyan Hao, Shiyun Xie, Yichao Wu, Mingzhong Cai* Stereoselective synthesis of functionalized (1E,5E)-1,5-dien-3-ynes containing ester or sulfonyl groups by palladium-catalyzed addition and cross-coupling reactions. New J. Chem., 2014, 38, 2686-2692.
11. Wenyan Hao, Guodong Ding, Mingzhong Cai* A phosphine-free heterogeneous formylation of aryl halides catalyzed by a thioether-functionalized MCM-41-immobilized palladium complex. Catal. Commun. 2014, 51, 53–57.
12. Wenyan Hao*, Tinli Zhang, Mingzhong Cai*. Synthesis of H-pyrazolo-[5,1-a]isoquinolines via a silver triflatecatalyzed tandem reaction of N’-(2-alkynylbenzylidene)hydrazide with alcohol. Tetrahedron. 2013, 69, 9219.
13. Wenyan Hao , Zhiwen Xi, Mingzhong Cai* A Practical Synthesis of Biaryls and Aromatic Acety- lenes by Stille Coupling in Room-Temperature Ionic Liquids. Synth.Commun .2012, 42, 2396-9.
14. Wenyan Hao, Junchao Sha, Shouri Sheng, Mingzhong Cai* The first heterogeneous carbonylative Sonogashira coupling reaction catalyzed by MCM-41-supported bidentate phosphine palladium(0) complex .J. Mole. Catal. A: Chem. 2009, 94-98.
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